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I'm not sure that your issue pertains to Remoting, which is used for EJBs, EJB3s, and JBossMessaging. It isn't used for web communication.
Thanks for the reply. The issue was solved by exposing the Naming Service via the external IP address Im able to reach the socket from both the LANs. Previously the InvokerURL was the internal IP address's URL which is the rmi.server.hostname by default.